i've been dosing kalk with my ato for quite a while. I just started dissolving the lime in vinegar about a month ago. It really increases the amount of lime that dissolves into the water (without precipitating). I changed nothing other than this, and my alk went from 7.7 to 9.0 over the course of a month (no water change in that time). I'm backing off a bit on the vinegar because i run biopellets and the alk sweet spot is 8.0.
I'd say if you're doing kalk, you might as well do vinegar. You can dose both together, it's really easy, and it makes your kalk more effective.